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The preparation of sulfur hexafluoride from elemental sulfur and elemental fluorine is not suitable for amateurs or beginners; it is definitely not a home experiment. Fluorine is corrosive and very toxic. It causes severe skin burns and eye damage and it is fatal if inhaled. Furthermore, it is an oxidiser and reacts violently with all combustible materials; thus, it may cause or intensify fire.
Self-made sulfur hexafluoride is not suitable for inhalation or similar experiments since it may contain various toxic impurities.
In the laboratory scale, a nickel boat is filled with sulfur and placed in a reaction tube. The tube is connected to a cold trap that is cooled with liquid nitrogen. The apparatus should be dry and ungreased. A stream of fluorine is then introduced.
The reaction $$\ce{S + 3F2 -> SF6}$$ is strongly exothermic (standard molar enthalpy of formation at $298.15\ \mathrm K$: $\Delta_\mathrm fH^\circ=-1220.5\ \mathrm{kJ/mol}$[1]). In the fluorine stream, sulfur burns with a blue flame.
Sulfur hexafluoride is collected in the cold trap. The product contains various impurities, such as $\ce{F2}$, $\ce{HF}$, $\ce{SOF2}$, $\ce{SO2F2}$, $\ce{SF2}$, $\ce{S2F2}$, $\ce{SF4}$, and $\ce{S2F10}$. Most of the impurities are easily hydrolysable; therefore the gas is passed through a washing bottle filled with $\ce{KOH}$ solution. However, $\ce{S2F10}$ has to be removed with activated charcoal or decomposed by pyrolysis at $400\ \mathrm{^\circ C}$ according to $$\ce{S2F10 -> SF4 + SF6}$$
[1] “Standard Thermodynamic Properties of Chemical Substances”, in CRC Handbook of Chemistry and Physics, 90th Edition (CD-ROM Version 2010), David R. Lide, ed., CRC Press/Taylor and Francis, Boca Raton, FL.
Sulfur hexafluoride (SF6) is a synthetic fluorinated compound with an extremely stable molecular structure. Because of its unique dielectric properties, electric utilities rely heavily on SF6 in electric power systems for voltage electrical insulation, current interruption, and arc quenching in the transmission and distribution of electricity. Yet, it is also the most potent greenhouse gas known to-date. Over a 100-year period, SF6 is 23,500 times more effective at trapping infrared radiation than an equivalent amount of carbon dioxide (CO2). SF6 is also a very stable chemical, with an atmospheric lifetime of 3,200 years. As the gas is emitted, it accumulates in the atmosphere in an essentially un-degraded state for many centuries. Thus, a relatively small amount of SF6 can have a significant impact on global climate change.
More information on long-lived fluorinated greenhouse gases, their emissions, emission sources, and trends is available on EPA’s overview of greenhouse gases page.
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Since the 1950’s, the U.S. electric power industry has used SF6 in circuit breakers, gas-insulated substations and other switchgear used in the transmission system to manage the high voltages carried between generating stations and customer load centers. Disconnectors and ground switches use SF6 primarily for insulation, and individually, they contain only slightly less SF6 than a circuit breaker. These devices are used to isolate portions of the transmission system where current flow has been interrupted (using a circuit breaker). Gas-insulated substations also use a significant amount of SF6, and GIS installations house SF6-insulated circuit breakers, busbars and monitoring equipment. The largest use of SF6 occurs in high-voltage circuit breakers, where, in addition to providing insulation, SF6 is used to quench the arc formed when an energized circuit breaker is opened.
Several factors affect SF6 emissions from electric power systems, such as the type and age of the SF6-containing equipment (e.g., old circuit breakers can contain up to 2,000 pounds of SF6, while modern breakers usually contain less than 100 pounds) and the handling and maintenance procedures practiced by electric utilities. Because of its long-life span and high global warming potential (GWP), even a relatively small amount of SF6 can impact the climate.
The electric power industry can reduce the nation’s SF6 emissions through cost-effective operational improvements and equipment upgrades. Through improvements in the leak rate of new equipment, refurbishing older equipment, and the use of more efficient operation and maintenance techniques, utilities often find economical solutions to reduce SF6 emissions.
Under the partnership, EPA shares information on best management practices and technical issues to help reduce emissions. Some cost-effective options to reduce SF6 emissions are:
Reducing SF6 emissions helps electric power systems:
SF6 is used in several different industries including:
The most common use for and largest emission source of SF6, both domestically and internationally, is as an electrical insulator in high voltage equipment that transmits and distributes electricity. Approximately 75 percent of all SF6 emissions in the United States is attributed to the electrical transmission and distribution sector in 2021 based on the Inventory of U.S. Greenhouse Gas Emissions and Sinks.
SF6 containing equipment is designed to avoid emitting any of this gas into the atmosphere. However, SF6 gas can inadvertently escape into the atmosphere as leaks develop during various stages of the equipment's lifecycle. In some cases, significant leaks can occur from aging equipment. Gas can be released at the time of equipment manufacturing, installation, maintenance and servicing, and de-commissioning.
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